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CuInS2-Poly(3-(ethyl-4-butanoate)thiophene) nanocomposite solar cells: Preparation by an in situ formation route, performance and stability issues

Identifieur interne : 003245 ( Main/Repository ); précédent : 003244; suivant : 003246

CuInS2-Poly(3-(ethyl-4-butanoate)thiophene) nanocomposite solar cells: Preparation by an in situ formation route, performance and stability issues

Auteurs : RBID : Pascal:11-0249594

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Abstract

In this contribution we present an in situ method for the preparation of CulnS2-poly(3-(ethyl-4-butanoate)thiophene) (P3EBT) nanocomposite layers and their application in nanocomposite solar cells. A precursor solution containing copper and indium salts, thiourea and the conjugated polymer was prepared in pyridine, which was coated onto glass/ITO substrates followed by a heating step at 180°C. The heating step induced the formation of the CuInS2 nanoparticles homogeneously dispersed in the conjugated polymer matrix. The formation of the nanocomposite was investigated in situ by X-ray scattering techniques and TEM methods showing that nano-scaled CuInS2 was formed. By addition of small amounts of zinc salt to the precursor solution, zinc containing CuInS2 (ZCIS) was formed. ZCIS- P3EBT active layers exhibited higher Voc than CuInS2-P3EBT layers and showed efficiencies of about 0.4%. Additionally the stability of the solar cells was tested over a time scale of 172 h.

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Pascal:11-0249594

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<title level="j" type="abbreviated">Sol. energy mater. sol. cells</title>
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<term>Active layer</term>
<term>Coated material</term>
<term>Conjugated polymer</term>
<term>Copper</term>
<term>Copper sulfide</term>
<term>Glass</term>
<term>Heating</term>
<term>In situ</term>
<term>Indium</term>
<term>Indium oxide</term>
<term>Indium sulfide</term>
<term>Nanocomposite</term>
<term>Nanoparticle</term>
<term>Nanostructured materials</term>
<term>Performance evaluation</term>
<term>Solar cell</term>
<term>Ternary compound</term>
<term>Thiophene</term>
<term>Thiourea</term>
<term>Tin addition</term>
<term>Transmission electron microscopy</term>
<term>X ray scattering</term>
<term>Zinc</term>
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<keywords scheme="Pascal" xml:lang="fr">
<term>Nanomatériau</term>
<term>Cellule solaire</term>
<term>In situ</term>
<term>Evaluation performance</term>
<term>Thiourée</term>
<term>Polymère conjugué</term>
<term>Addition étain</term>
<term>Chauffage</term>
<term>Nanoparticule</term>
<term>Diffusion RX</term>
<term>Microscopie électronique transmission</term>
<term>Couche active</term>
<term>Composé ternaire</term>
<term>Sulfure de cuivre</term>
<term>Sulfure d'indium</term>
<term>Thiophène</term>
<term>Nanocomposite</term>
<term>Cuivre</term>
<term>Indium</term>
<term>Matériau revêtu</term>
<term>Verre</term>
<term>Oxyde d'indium</term>
<term>Zinc</term>
<term>CuInS2</term>
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<div type="abstract" xml:lang="en">In this contribution we present an in situ method for the preparation of CulnS
<sub>2</sub>
-poly(3-(ethyl-4-butanoate)thiophene) (P3EBT) nanocomposite layers and their application in nanocomposite solar cells. A precursor solution containing copper and indium salts, thiourea and the conjugated polymer was prepared in pyridine, which was coated onto glass/ITO substrates followed by a heating step at 180°C. The heating step induced the formation of the CuInS
<sub>2</sub>
nanoparticles homogeneously dispersed in the conjugated polymer matrix. The formation of the nanocomposite was investigated in situ by X-ray scattering techniques and TEM methods showing that nano-scaled CuInS
<sub>2</sub>
was formed. By addition of small amounts of zinc salt to the precursor solution, zinc containing CuInS
<sub>2</sub>
(ZCIS) was formed. ZCIS- P3EBT active layers exhibited higher V
<sub>oc</sub>
than CuInS
<sub>2</sub>
-P3EBT layers and showed efficiencies of about 0.4%. Additionally the stability of the solar cells was tested over a time scale of 172 h.</div>
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<sub>2</sub>
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<sub>2</sub>
nanoparticles homogeneously dispersed in the conjugated polymer matrix. The formation of the nanocomposite was investigated in situ by X-ray scattering techniques and TEM methods showing that nano-scaled CuInS
<sub>2</sub>
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<sub>2</sub>
(ZCIS) was formed. ZCIS- P3EBT active layers exhibited higher V
<sub>oc</sub>
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<sub>2</sub>
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<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE">
<s0>Thiourée</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG">
<s0>Thiourea</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA">
<s0>Tiourea</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Polymère conjugué</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Conjugated polymer</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Polímero conjugado</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE">
<s0>Addition étain</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG">
<s0>Tin addition</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA">
<s0>Adición estaño</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Chauffage</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Heating</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Calefacción</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE">
<s0>Nanoparticule</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG">
<s0>Nanoparticle</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA">
<s0>Nanopartícula</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE">
<s0>Diffusion RX</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG">
<s0>X ray scattering</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA">
<s0>Difusión rayo X</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE">
<s0>Microscopie électronique transmission</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG">
<s0>Transmission electron microscopy</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA">
<s0>Microscopía electrónica transmisión</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE">
<s0>Couche active</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG">
<s0>Active layer</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA">
<s0>Capa activa</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE">
<s0>Composé ternaire</s0>
<s5>22</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG">
<s0>Ternary compound</s0>
<s5>22</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA">
<s0>Compuesto ternario</s0>
<s5>22</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE">
<s0>Sulfure de cuivre</s0>
<s5>23</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG">
<s0>Copper sulfide</s0>
<s5>23</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA">
<s0>Cobre sulfuro</s0>
<s5>23</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE">
<s0>Sulfure d'indium</s0>
<s5>24</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG">
<s0>Indium sulfide</s0>
<s5>24</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA">
<s0>Indio sulfuro</s0>
<s5>24</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE">
<s0>Thiophène</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG">
<s0>Thiophene</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA">
<s0>Tiofeno</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE">
<s0>Nanocomposite</s0>
<s5>26</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG">
<s0>Nanocomposite</s0>
<s5>26</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA">
<s0>Nanocompuesto</s0>
<s5>26</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE">
<s0>Cuivre</s0>
<s2>NC</s2>
<s5>27</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG">
<s0>Copper</s0>
<s2>NC</s2>
<s5>27</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA">
<s0>Cobre</s0>
<s2>NC</s2>
<s5>27</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE">
<s0>Indium</s0>
<s2>NC</s2>
<s5>28</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG">
<s0>Indium</s0>
<s2>NC</s2>
<s5>28</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA">
<s0>Indio</s0>
<s2>NC</s2>
<s5>28</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE">
<s0>Matériau revêtu</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG">
<s0>Coated material</s0>
<s5>29</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA">
<s0>Material revestido</s0>
<s5>29</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE">
<s0>Verre</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG">
<s0>Glass</s0>
<s5>30</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA">
<s0>Vidrio</s0>
<s5>30</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE">
<s0>Oxyde d'indium</s0>
<s5>31</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG">
<s0>Indium oxide</s0>
<s5>31</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA">
<s0>Indio óxido</s0>
<s5>31</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE">
<s0>Zinc</s0>
<s2>NC</s2>
<s5>32</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG">
<s0>Zinc</s0>
<s2>NC</s2>
<s5>32</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA">
<s0>Zinc</s0>
<s2>NC</s2>
<s5>32</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE">
<s0>CuInS2</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE">
<s0>ITO</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fN21>
<s1>171</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>ISOS International Summit on Organic Photovoltaic Stability (OPV) Stability</s1>
<s2>3</s2>
<s3>Roskilde DNK</s3>
<s4>2010-04-19</s4>
</fA30>
</pR>
</standard>
</inist>
</record>

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